What kind of litter do you use? I know some cats have issues with soiling themselves but it's usually fecal matter and not urine. I wonder why he would get in touch with the urine while using the box?
Here's an article about cleaning kitty bums which could help with your issue as well -
[article="32464"]Be Kind To Your Cats Behinds Dirty Cat Butts Prevention And Treatment[/article]